I'm not sure about your Mercury EFI engine, but it still could be something relatively simple. If it is peeing after the engine warms up and the water pressure increases as RPM increases, that's a good start. It could also be that the tube from the lower unit to the engine didn't get lined up correctly, so not all water is getting into the water passages in the cylinder head, since you just changed the impeller.
A couple of years ago I had overheating on my '85 Evinrude XP150 at only WOT despite a new impeller, thermostats, and pressure relief valves and springs. The issue ended up being little rubber diverter tubes in the water passages in the engine block had swollen after nearly 40 years and needed to be replaced with fresh tubes, and I could see it plain as day as soon as I pulled the cylinder heads. After changing the tubes, installing new gaskets, and properly torquing the cylinder head bots, it's been fine.


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